Hf acid is extremely susceptible to stress corrosion cracking in water with a very low concentration of chloride ion. Tests for stress corrosion stress corrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. Chloride stress corrosion cracking is a well known form of scc, typically caused by inadvertently contaminating equipment with chlorides. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. Elevated stress susceptible material corrosive environment. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Drop evaporation test method, author steinsmo, u and drugli, j m, abstractnote stress corrosion cracking scc of chloride. Stress corrosion crack an overview sciencedirect topics. Chloride stress corrosion cracking one of the most recognized forms of scc, chloride stress corrosion cracking appears as highly branched spiderweb cracks. Testing and evaluation methods for stress corrosion. Chlorideinduced scc is tested experimentally in the laboratory using a chloridecontaining environment. Presented in this report are the results of stress corrosion cracking testing per astm g36 standard practice for performing stress corrosion cracking tests in a boiling magnesium chloride. Stress corrosion cracking of carbon steel in ethanol. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing.
Developing field test procedures for chloride stress. Materials that normally provide acceptable resistance in hot chloride service may crack in this test. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Chloride stress corrosion cracking although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially.
Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking regulatory issue resolution protocol august 5, 2014. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking is the growth of crack formation in a corrosive environment. Chloride stress corrosion cracking test as per astm g36. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Nickelcontaining austenitic stainless steels, on the other hand, are highly susceptible to stress corrosion cracking. It is a method for detecting the effects of composition, heat treatment, surface finish, microstructure, and stress on the susceptibility of these materials to chloride stress corrosion cracking. Stress corrosion cracking scc is difficult to predict and identify, and it can lead to catastrophic failure, often without any prior warning. Astm g36 942018 standard practice for evaluating stress. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride. Astm g123 002015 standard test method for evaluating stress. Assessment of susceptibility to chloride stress corrosion. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. The stress corrosion cracking is completely inhibited by the. Hydrogen formed on the surface of the steel by a cathodic corrosion reaction can diffuse into the material, causing embrittlement, and, if the region is subject to tensile stress, cracking. External chloride stress corrosion cracking ecscc is a type of corrosion under insulation cui that appears in austenitic stainless steels.
Grades with high resistance to chlorideinduced stress corrosion cracking. Transformable ferritic steels are susceptible to hydrogeninduced scc in a wide range of aqueous media. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Laboratory tests duplicated plant experience and demonstrated that type304 stainless steel which was sensitized and pickled in the commonly used hnosub 3. Stress corrosion cracking in aluminum alloys is characteristically intergranular. Oil and gas production and petrochemical plants in the arabian gulf are exposed to severe environmental conditions of high temperature and humidity. Clscc chloride stress corrosion cracking mechanism china. This makes these plants susceptible to chloride induced stress corrosion cracking cscc. The effects of dissolved oxygen content in the water, heat treatment, especially slight sensitization, and most importantly chloride ion concentration on the susceptibility of type 304 stainless steel to stress corrosion cracking scc were investigated.
Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. The laboratory testing fails to provide the exact field. Pdf stress corrosion cracking scc of nickelbased alloys. A cost efficient field test setup for cscc was designed and developed for.
Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Astm g 48 stainless steel pitting and crevice corrosion in ferric chloride. This test method is concerned primarily with the test solution and glassware, although a specific style of ubend test. A range of test methods is available in the form of international and national standards and procedures, comprising a wide variety of test. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Presented in this report are the results of stress corrosion cracking testing per astm g36 standard practice for performing stress corrosion cracking tests in a boiling magnesium chloride solution of welded bare and finned tubes fabricated from steel. Developing field test procedures for chloride stress corrosion. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s. This paper presents the results of a study on the effects of water, acetic acid ch 3 cooh, oxygen, corrosion inhibitor, chloride, methanol ch 3 oh, denaturant, and corrosion product on the stress corrosion cracking scc of steel in ethanol c 2 h 5 oh. G16 guide for applying statistics to analysis of corrosion data. G30 practice for making and using ubend stress corrosion test specimens. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Stress corrosion cracking, as the name suggests, is a.
Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Current density and applied load were monitored during corrosion tests. Chlorideinduced stress corrosion cracking tests and example. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. In nace mr0175iso 15156, however, but both ssc and chloride stress corrosion cracking scc are considered.
G15 terminology relating to corrosion and corrosion testing. This mode of attack is termed stress corrosion cracking scc. Ctlastm g36 stress corrosion cracking in a boiling. The reason is the lower concentration of corrosive hydrogen near the fracture surface in comparison with tests in chloride solutions.
Stress corrosion cracking international institute of. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Sulfide stress cracking nace mr01752002, mr0175iso. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. Especially in case of chloride stress corrosion cracking, it has been shown that accumulation of chloride ions and consequent destruction of the passive film would be greater in the presence of deep grooves on the surface shoji 2003. We offer testing for both pitting and intergranular corrosion types as well as stress corrosion cracking. If you have insulated solid stainless steel equipment operating in the cui temperature range you are likely to eventually experience external chloride stress corrosion cracking ecscc. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions.
Stress corrosion cracking facts and how to reduce the risk. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. A range of test methods is available in the form of international and national standards and procedures, comprising a wide variety of test methods for assessing scc and also. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Stress corrosion cracking the international institute of. The decay heat of the spent nuclear fuel in dry storage, by design, will dissipate through the stainless steel canister via natural convection.
Sulfide stress cracking nace mr01752002, mr0175iso 15156. Chloride stress corrosion cracking in austenitic stainless. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. The factor that was found to have the greatest effect on causing scc was corrosion. The importance of a conjoint action of corrosion and stress. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Sulphide stress corrosion cracking test sscc as per nace tm 0177 hydrogen induced cracking test hic test as per nace tm 0284 mercurous nitrate test mass of coating and coating thickness measurement salt.
Stress corrosion cracking of an austenitic stainless steel. Sulfide stress cracking an overview sciencedirect topics. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950. Elements scc capabilities help to quickly evaluate the susceptibility of metallic materials to cracking and determine the size and scope of the problem before the failure occurs, avoiding major. Monitoring of chloride stress corrosion cracking of austenitic.
Elements scc capabilities help to quickly evaluate the susceptibility of metallic materials to cracking. Monitoring of chloride stress corrosion cracking of. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking. Corrosion testing is necessary procedures for the aerospace, automotive, and materials industries which mimic environmental conditions that place repetitive stress on products and materials, causing eventual decomposition and damage to its integrity, resulting in stress corrosion cracking. Standard practice for evaluating stresscorrosioncracking. For a given alloy, the testing result depends on the stress state and environment.
Testing can be carried out, for example, in boiling 40% cacl 2 or chloridecontaining water. However, no data were found that could be used to predict the time required for crack initiation by localised corrosion in real structures. The test may not be relevant to stresscorrosion cracking in. Corrosion properties chloride stress corrosion cracking resistance the nickelfree ferritic steels are essentially immune to chloride stress corrosion cracking even in the extremely severe boiling 42% magnesium chloride test. This makes these plants susceptible to chlorideinduced stress corrosion cracking cscc. The tensile stress may be residual stress resulting from heat treatment. Testing can be carried out, for example, in boiling 40%. This test method is performed in 25 % by mass sodium chloride acidified to ph 1. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Stress corrosion cracking scc can occur in a most metals and alloys due to the combined action of corrosion, tensile stress residual or applied and a susceptible microstructure. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Chloride stress corrosion cracking in austenitic stainless steel.
According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Based on this series of test results, it was concluded that austeniticstainless steel is susceptible to chlorideinduced scc caused by salt deliquescence at rh. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. This mode of attack is termed stress corrosion cracking. Astm g 150 critical pitting temperature cpt of stainless steels. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at. Tests for stresscorrosion stress corrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride. Corrosion and stress corrosion cracking can be significant issues for stainless steels used in a range of industries. Chlorideinduced stress corrosion cracking tests and. The boiling magnesium chloride test cracks materials with the nickel levels.
Alloy 825 is more resistant to stress corrosion cracking. An extensive failure analysis shows how many service failures occurred in the industry and what kind of alloys and stresses led to initiation and propagation of stress corrosion. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Constant elongation rate tests and constant load, subcritical crack growth tests were used to investigate the stress corrosion cracking scc susceptibility of metastable type 301. Stress corrosion cracking can lead to catastrophic brittle failure. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking. Chloride cracking of austenitic stainless steels 300 series ss is an offshoot of cui, and theres nothing really magical about it.
The chloride stresscorrosion cracking behavior of stainless steels. Astm g103 scc test of alznmg alloys in boiling 6% sodium chloride. While clearly intended to be used only for oil field equipment, industry has applied mr0175 in to many other areas including refineries, lng plants, pipelines and natural gas. Standard test method for evaluating stresscorrosion cracking of stainless alloys. Effect of ph and chloride contents on stress corrosion.
Testing and evaluation methods for stress corrosion cracking. Chloride induced stress corrosion cracking tests and example aging management program darrell s. Although no stainless steel grade is totally immune. Feb 15, 2017 a great concern for the longterm integrity of canisters located near the coastline is chloride induced stress corrosion cracking of austenitic stainless steels 3,4,5. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Stress corrosion cracking scc of nickelbased alloys. Nace tm0284 hydrogen induced cracking hic astm standard tests, including.
The development of standardised methods of testing is a key element in the prevention of stress corrosion cracking scc in order to provide a unified reference framework. Stress corrosion cracking susceptibility of 304l substrate. The laboratory testing fails to provide the exact field environmental conditions. Pdf assessment of stress corrosion cracking susceptibility for. Susceptibility assessment criteria for chlorideinduced. Chloride stress corrosion cracking inspectioneering. Aluminum alloys that contain appreciable amounts of soluble alloying elements, primarily copper, magnesium, silicon, and zinc, are susceptible to stresscorrosion cracking scc.
The interaction of corrosion fatigue and stresscorrosion. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at. Stress corrosion cracking facts and how to reduce the. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Astm g123 002015 standard test method for evaluating. Stress corrosion cracking of an austenitic stainless steel in. G36 practice for evaluating stress corrosion cracking resistance of metals and alloys in a boiling magnesium chloride solution. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution.
The relative resistance of a stainless steel to chloride scc is often quantified by the use of standard boiling salt solutions. Novel chloride stress corrosion cracking test was validated by acoustic emission. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Astm g 48 stainless steel pitting and crevice corrosion in ferric chloride or custom environments.
1384 311 1196 341 940 1158 939 167 412 1478 86 332 1101 82 1134 1282 55 379 383 512 806 630 386 1025 272 903 1418 1328 1103 123 576 489 63 504 910 1368 163 823 7